Plant-Mediated Enantioselective Transformation of Indan-1-One and Indan-1-ol
نویسندگان
چکیده
منابع مشابه
2-[1-(1-Oxoindan-2-yl)ethyl]indan-1-one
In the title compound, C(20)H(18)O(2), the fused-ring systems are essentially planar (r.m.s. deviations of the nine fitted atoms = 0.009 and 0.027 Å) and exhibit an orthogonal relationship [dihedral angle = 79.83 (5)°]. To a first approximation, the ketone-O atoms are directed to opposite sides of the mol-ecule. A three-dimensional architecture arises in the crystal packing owing to C-H⋯O, C-H⋯...
متن کامل(E)-2-(4-Bromobenzylidene)indan-1-one
In the title compound, C(16)H(11)BrO, the dihydro-indene ring system is approximately planar, with a maximum deviation of 0.008 (2) Å. The mean plane of this ring system forms a dihedral angle of 3.73 (11)°, with the bromo-substituted benzene ring. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into sheets parallel to the ab plane and further stabilization is prov...
متن کاملEnantioselective Desymmetrization of Glutarimides Catalyzed by Oxazaborolidines Derived from cis-1-Amino-indan-2-ol.
Enantioselective reductive desymmetrization of glutarimides has been achieved employing an oxazaborolidine catalyst derived from cis-1-amino-indan-2-ol. The reaction was found to proceed through a stereoablative process that upgraded the enantioselectivity of an intermediate hydroxy-lactam. The reaction was generally tolerant of a number of substituents in the 4-position, giving enantiomeric ex...
متن کامل(E)-2-(4-Chlorobenzylidene)indan-1-one
In the title compound, C(16)H(11)ClO, the dihedral angle between the almost planar dihydro-indene ring system (r.m.s. deviation = 0.009 Å) and the chloro-benzene ring is 3.51 (14)°. In the crystal, mol-ecules are connected by C-H⋯O and weak C-H⋯Cl inter-actions, forming infinite layers parallel to (101).
متن کامل2-[(E)-2,5-Dimethoxybenzylidene]indan-1-one
In the title compound, C(18)H(16)O(3), the mean plane of the nine-membered indane system makes a dihedral angle of 3.71 (17)° with the benzene ring of the dimethoxy-phenyl group. The mol-ecular conformation is stabilized by intra-molecular C-H⋯O hydrogen contacts. The crystal structure is stabilized by inter-molecular C-H⋯O inter-actions, which link neighbouring mol-ecules into one-dimensional ...
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ژورنال
عنوان ژورنال: Catalysts
سال: 2019
ISSN: 2073-4344
DOI: 10.3390/catal9100844